Crystal structure and electrochemical properties of the supramolecular compound [Himi] 6 [As 2 Mo 18 O 62 ]·11H 2 O | Zendy

Yang Yanyan | Zendy; Xu Lin | Zendy; Jia Liping | Zendy; Gao Guanggang | Zendy; Li Fengyan | Zendy; Qu Xiaoshu | Zendy; Qiu Yunfeng | Zendy

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Crystal structure and electrochemical properties of the supramolecular compound [Himi] 6 [As 2 Mo 18 O 62 ]·11H 2 O

Author(s) -

Yang Yanyan,

Xu Lin,

Jia Liping,

Gao Guanggang,

Li Fengyan,

Qu Xiaoshu,

Qiu Yunfeng

Publication year - 2007

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200710937

Subject(s) - monoclinic crystal system , supramolecular chemistry , crystallography , imidazole , chemistry , crystal structure , hydrogen bond , protonation , electrochemistry , intermolecular force , crystal (programming language) , infrared spectroscopy , stereochemistry , molecule , ion , organic chemistry , electrode , computer science , programming language

A supramolecular compound, [Himi] 6 [As 2 Mo 18 O 62 ]·11H 2 O ( 1 ) (imi = imidazole), has been synthesized and characterized by single crystal X‐ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b = 20.9521(11) Å, c = 25.2464(13) Å, β = 93.8130(10)°, V = 7892.1(7) Å 3 , Z = 4. X‐ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding). (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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