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Preparation, single crystal growth and characterization of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper
Author(s) -
Wang X. Q.,
Xu D.,
Ren Q.,
Zhang G. H.,
Sun X. B.,
Hou X. Q.,
Guo W. F.,
Lü H.
Publication year - 2007
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200610827
Subject(s) - thermogravimetric analysis , copper , differential thermal analysis , single crystal , characterization (materials science) , chemistry , infrared spectroscopy , thermal analysis , absorption spectroscopy , spectroscopy , diffraction , absorption (acoustics) , band gap , crystal (programming language) , inorganic chemistry , crystallography , thermal , materials science , nanotechnology , organic chemistry , optics , programming language , physics , quantum mechanics , meteorology , computer science , optoelectronics , composite material
The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility χ (3) is about 1.3×10 ‐3 esu at 1064 nm. The characterization of (I) has been performed by electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The thermal behavior of (I) has been investigated by means of thermogravimetric analysis (TGA) and differential thermal analysis (DTA) measurements in air. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)