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A novel metal‐organic coordination complex crystal: tri‐allylthiourea zinc chloride (ATZC)
Author(s) -
Sun H. Q.,
Yuan D. R.,
Wang X. Q.,
Cheng X. F.,
Gong C. R.,
Zhou M.,
Xu H. Y.,
Wei X. C.,
Luan C. N.,
Pan D. Y.,
Li Z. F.,
Shi X. Z.
Publication year - 2005
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200410450
Subject(s) - thermogravimetric analysis , zinc , chemistry , crystal structure , coordination complex , chloride , infrared spectroscopy , differential scanning calorimetry , metal , crystal (programming language) , crystallography , single crystal , powder diffraction , urea , nuclear chemistry , inorganic chemistry , organic chemistry , programming language , physics , computer science , thermodynamics
A new metal‐organic coordination nonlinear optical crystal, tri‐allylthiourea zinc chloride (ZnCl 2 (AT) 3 , where AT is CH 2 =CHCH 2 NHCSNH 2 , abbreviated as ATZC), is reported. It was synthesized in water and recrystallized in ethanol. For the crystal structure, optical and thermal characterization were determined by elemental analyses, X‐ray diffraction, infrared spectroscopy, differential scanning calorimeter, thermogravimetric analysis, and powder SHG efficiency meansurement. It belongs to the trigonal system, space group R3, with a = 11.0498(4) Å, c = 16.0416(11) Å, z = 3 and V = 1696.24(15) Å 3 . It exhibits powder SHG efficiency the same order as Urea crystal. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)