Synthesis and crystal structure of [CuCl( phen ) 2 ] 3 H 3 V 10 O 28  · 7 H 2 O | Zendy

Rakovský E. | Zendy; Joniaková D. | Zendy; Gyepes R. | Zendy; Schwendt P. | Zendy; Mička Z. | Zendy

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Synthesis and crystal structure of [CuCl( phen ) 2 ] 3 H 3 V 10 O 28 · 7 H 2 O

Author(s) -

Rakovský E.,

Joniaková D.,

Gyepes R.,

Schwendt P.,

Mička Z.

Publication year - 2005

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200410415

Subject(s) - chemistry , protonation , aqueous solution , crystallography , crystal structure , proton , group (periodic table) , crystal (programming language) , phenanthroline , bond length , stereochemistry , ion , organic chemistry , physics , quantum mechanics , computer science , programming language

The new compound, [CuCl( phen ) 2 ] 3 H 3 V 10 O 28 · 7 H 2 O, was prepared by reaction of an aqueous KVO 3 solution (pH 3) with an aqueous solution of CuSO 4 · 5 H 2 O in which 1,10‐phenanthroline ( phen ) and KCl were added. The crystal structure of the compound was determined, and the proton position in H 3 V 10 O 28 3– were calculated by the bond length/bond number method and also determined from difference electron density map. The protons are bound to colinearly arranged μ –OV 2 and μ –OV 3 groups which is the common protonation type in trihydrogen decavanadates. The structure crystallizes in P1 space group symmetry. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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