New zeotype borophosphates with chiral tetrahedral topology: (H) 0.5 M 1.25 (H 2 O) 1.5 [BP 2 O 8 ]·H 2 O (M = Co(II) and Mn(II)) | Zendy

Yilmaz A. | Zendy; Tatar Yįldįrįm L. | Zendy; Bu X. | Zendy; Kizilyalli M. | Zendy; Stucky G. D. | Zendy

Premium

New zeotype borophosphates with chiral tetrahedral topology: (H) 0.5 M 1.25 (H 2 O) 1.5 [BP 2 O 8 ]·H 2 O (M = Co(II) and Mn(II))

Author(s) -

Yilmaz A.,

Tatar Yįldįrįm L.,

Bu X.,

Kizilyalli M.,

Stucky G. D.

Publication year - 2005

Publication title -

crystal research and technology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.377

H-Index - 64

eISSN - 1521-4079

pISSN - 0232-1300

DOI - 10.1002/crat.200410386

Subject(s) - isostructural , crystallography , antiferromagnetism , hydrothermal synthesis , chemistry , single crystal , hydrothermal circulation , crystal structure , octahedron , magnetic susceptibility , space group , x ray crystallography , diffraction , physics , optics , seismology , geology , condensed matter physics

Two new isostructural open‐framework zeotype transition metal borophosphate compounds, (H) 0.5 M 1.25 (H 2 O) 1.5 [BP 2 O 8 ]·H 2 O (M = Co(II) and Mn(II)) were synthesized by mild hydrothermal method. The structure of compounds were characterized by single‐crystal X‐ray diffraction which have ordered, alternating, vertex‐sharing BO 4 , PO 4 , and (MO 4 )OM(H 2 O) 2 groups with hexagonal, P 6 1 2 2 (No 178) space group and unit cell parameters for Co a = 9.4960(6) Å, c = 15.6230(13) Å, for Mn a = 9.6547(12) Å, c = 15.791(3) Å, Z = 1 for both of them. TGA/DTA analysis, IR spectroscopy were used for characterization. Magnetic susceptibility measurements for both of the compound indicate strong antiferromagnetic interaction between metal centers. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research