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Structure and spectra character of cobalt nickel sulfate twelvehydrate (CNSH) single crystal
Author(s) -
Su Genbo,
Zhuang Xinxin,
He Youping,
Li Zhengdong,
Li Guohui,
Ma Jingbo,
Wang Guofu,
Huang Zixiang
Publication year - 2003
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200310141
Subject(s) - monoclinic crystal system , crystal structure , nickel , crystallography , crystal (programming language) , chemistry , aqueous solution , ultraviolet , single crystal , cobalt , spectral line , character (mathematics) , wavelength , materials science , inorganic chemistry , physics , optoelectronics , organic chemistry , geometry , mathematics , astronomy , computer science , programming language
The title compound CoNi(SO 4 ) 2 · 12H 2 O has been prepared and its crystal structure determined by single crystal X‐ray differaction at room temperature. The CNSH crystal structure belongs to the monoclinic space group C2/c,a = 9.966(2) Å, b = 7.2265(14) Å, c = 24.218(5) Å, β = 98.32(3)°, V = 1725.9(6) Å 3 , z = 4, Dc = 2.024 gcm −3 . The optical transmission character of CNSH crystal in aqueous solution is discontinuous in the range from ultraviolet to near IR wavelengths. The relationship between the structure and the optical transmission property is further discussed. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)