Premium
Influence of crystallization conditions on the mechanism and rate of crystal growth of potassium sulphate
Author(s) -
Omar W.,
Ulrich J.
Publication year - 2003
Publication title -
crystal research and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.377
H-Index - 64
eISSN - 1521-4079
pISSN - 0232-1300
DOI - 10.1002/crat.200310004
Subject(s) - supersaturation , growth rate , potassium sulfate , potassium , crystallization , metastability , chemistry , crystal growth , saturation (graph theory) , sulfate , ion , inorganic chemistry , mineralogy , chemical engineering , crystallography , organic chemistry , geometry , mathematics , combinatorics , engineering
Abstract Growth rate of potassium sulfate crystals was studied in a fluidized bed crystallizer. Higher growth rates were observed at larger bed heights. Larger crystals grow faster than smaller size crystals due to the changed fluid dynamics. The growth rate was found to be very sensitive to the pH value of the solution. The growth rate increases with increasing the pH value and the increase of growth in the acidic medium is faster than in the basic medium. The presence of small amounts of Cr 3+ ions reduces the growth rate of potassium sulfate dramatically. The presence of Cr 3+ ions lowers the saturation temperature and increases the width of the metastable zone, i.e. shifts the metastability of the solution to be at lower level of supersaturation.