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Visible‐Light‐Driven Competitive Stereo‐ and Regioisomerization of ( E )‐β‐Nitroenones
Author(s) -
Raviola Carlotta,
Carrera Cristina,
Serra Massimo,
Palmieri Alessandro,
Lupidi Gabriele,
Maestri Giovanni,
Protti Stefano
Publication year - 2021
Publication title -
chemphotochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.13
H-Index - 18
ISSN - 2367-0932
DOI - 10.1002/cptc.202100081
Subject(s) - excited state , state (computer science) , chemistry , computer science , photochemistry , physics , algorithm , atomic physics
A combined experimental and computational investigation of the photoreactivity of ( E )‐β‐nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to ( E )‐β‐nitroenones and deconjugation to β‐nitro‐β,γ‐enones. Both processes are generated from the triplet excited state of the starting substrates.