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Rates of Ring Opening of Radical Cation Intermediates Govern Differences in Thermoluminescence between 1‐ and 2‐Naphthyl‐Substituted Methylenecyclopropanes
Author(s) -
Matsui Yasunori,
Shimono Kazuki,
Takae Kosuke,
Namai Hayato,
Sera Toshiki,
Ogaki Takuya,
Ohta Eisuke,
Mizuno Kazuhiko,
Ikeda Hiroshi
Publication year - 2020
Publication title -
chemphotochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.13
H-Index - 18
ISSN - 2367-0932
DOI - 10.1002/cptc.202000019
Subject(s) - front cover , ring (chemistry) , phosphorescence , reactivity (psychology) , chemistry , photochemistry , fluorescence , medicinal chemistry , thermoluminescence , cover (algebra) , organic chemistry , materials science , physics , luminescence , optics , medicine , alternative medicine , pathology , engineering , optoelectronics , mechanical engineering
The front cover artwork is provided by the group of Prof. Dr. Hiroshi Ikeda in Osaka Prefecture University (Japan). The picture represents the difference in reactivity between 1‐ and 2‐naphthyl‐substituted methylenecyclopropanes. The weak bond in the former substance can be broken even by a small samurai resulting in pink fluorescence, whereas the strong bond in the latter cannot be broken even by a big samurai (resulting in green phosphorescence). Read the full text of the Communication at 10.1002/cptc.201900230.