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Cover Feature: Isomerization Dynamics of Electronically Coupled but Thermodynamically Decoupled Bisazobenzenes (ChemPhotoChem 6/2019)
Author(s) -
Boumrifak Chokri,
Yang Chong,
Bellotto Silvia,
Wegner Hermann A.,
Wachtveitl Josef,
Dreuw Andreas,
Slavov Chavdar
Publication year - 2019
Publication title -
chemphotochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.13
H-Index - 18
ISSN - 2367-0932
DOI - 10.1002/cptc.201900156
Subject(s) - azobenzene , isomerization , photoswitch , excitation , moiety , cover (algebra) , coupling (piping) , chemistry , feature (linguistics) , quantum , chemical physics , photoisomerization , photochemistry , computational chemistry , materials science , molecule , stereochemistry , physics , quantum mechanics , organic chemistry , mechanical engineering , linguistics , philosophy , engineering , metallurgy , catalysis
The Cover Feature illustrates the splitting of the isomerization pathways after selective excitation of a molecular double‐photoswitch. Photoresponsive structures composed of multiple photoswitchable units offer the possibility of more diverse and complex control applications. For example, o‐bisazobenzenes show unusual electronic coupling affecting the properties of the individual azobenzene units. Time‐resolved spectroscopic experiments supported by quantum chemical calculations revealed that electronic coupling removes the bias introduced by selective excitation of one azobenzene moiety. More information can be found in the Article by C. Boumrifak et al. on page 411 in Issue 6, 2019 (DOI: 10.1002/cptc.201900077).