Highly Performing Iodoperfluoroalkylation of Alkenes Triggered by the Photochemical Activity of Perylene Diimides | Zendy

Rosso Cristian | Zendy; Filippini Giacomo | Zendy; Cozzi Pier Giorgio | Zendy; Gualandi Andrea | Zendy; Prato Maurizio | Zendy

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Highly Performing Iodoperfluoroalkylation of Alkenes Triggered by the Photochemical Activity of Perylene Diimides

Author(s) -

Rosso Cristian,

Filippini Giacomo,

Cozzi Pier Giorgio,

Gualandi Andrea,

Prato Maurizio

Publication year - 2019

Publication title -

chemphotochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.13

H-Index - 18

ISSN - 2367-0932

DOI - 10.1002/cptc.201900018

Subject(s) - perylene , photochemistry , irradiation , catalysis , chemistry , visible spectrum , materials science , organic chemistry , optoelectronics , molecule , physics , nuclear physics

We describe a novel efficient photochemical procedure for the direct iodoperfluoroalkylation of terminal olefins. The process uses a simple and inexpensive perylenediimide (PDI) in an extremely low catalytic loading and occurs with visible light irradiation. The reported methodology is highly viable from a synthetic point of view, since it proceeds under mild reaction conditions with a significant rate of production. Preliminary mechanistic investigations are also reported.

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