Two Useful Directing Modes in Singlet Oxygen Reactivity: Electrostatic Effects in the Ene Reaction with Allylic Alcoholates and a Chemoselectivity Change with α‐Alkoxy Michael Esters | Zendy

Kleczka Margarethe | Zendy; But Diana | Zendy; Dylong Dominik | Zendy; Fendinger Carolina | Zendy; Marmann Verena | Zendy; Wartke Christian | Zendy; Griesbeck Axel G. | Zendy

Premium

Two Useful Directing Modes in Singlet Oxygen Reactivity: Electrostatic Effects in the Ene Reaction with Allylic Alcoholates and a Chemoselectivity Change with α‐Alkoxy Michael Esters

Author(s) -

Kleczka Margarethe,

But Diana,

Dylong Dominik,

Fendinger Carolina,

Marmann Verena,

Wartke Christian,

Griesbeck Axel G.

Publication year - 2018

Publication title -

chemphotochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.13

H-Index - 18

ISSN - 2367-0932

DOI - 10.1002/cptc.201800214

Subject(s) - ene reaction , singlet oxygen , allylic rearrangement , chemoselectivity , singlet state , alkoxy group , chemistry , reactivity (psychology) , oxygen , photochemistry , proton , medicinal chemistry , organic chemistry , catalysis , physics , atomic physics , quantum mechanics , medicine , alkyl , alternative medicine , pathology , excited state

The front cover artwork is provided by Axel Griesbeck and Diana But at the University of Cologne (Germany). The image shows a cartoon of the hydrogen‐transfer process initiating the singlet oxygen ene reaction with several strong regio‐ and stereodirecting effects following the rule of thumb: If you give singlet oxygen your little finger it will soon have your whole hand (as adapted from a quote by Sigmund Freud). Read the full text of the Article at 10.1002/cptc.201800133 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research