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Multistimuli‐Responsive Materials from Benzothiadiazole‐Based Charge‐Transfer Chromophores: Interdependence of Optical Properties and Aggregation
Author(s) -
Bardi Brunella,
Dall'Agnese Chunxiang,
Tassé Marine,
Ladeira Sonia,
Painelli Anna,
MoineauChane Ching Kathleen I.,
Terenziani Francesca
Publication year - 2018
Publication title -
chemphotochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.13
H-Index - 18
ISSN - 2367-0932
DOI - 10.1002/cptc.201800145
Subject(s) - chromophore , materials science , luminescence , alkyl , photochemistry , annealing (glass) , thermal treatment , acceptor , fluorescence , polymer , chemical engineering , excitation , polymer chemistry , chemistry , optoelectronics , organic chemistry , optics , composite material , physics , electrical engineering , engineering , condensed matter physics
A family of multipolar V‐shaped chromophores bearing an A′‐D‐A‐D‐A′ structure were investigated, where 2,1,3‐benzothiadiazole, acting as the central electron acceptor (A), is linked to two thiophene‐based electron‐donating moieties (D) end‐capped with alkyl‐cyanoacetate substituents (A′). The spectroscopic properties of thin films and powders were investigated and were compared to solutions and nanoaggregates. The optical properties strongly depended on the aggregation state and could be tuned by means of thermal treatment (annealing) of the films and through mechanical treatment (grinding) of the powders, demonstrating that these materials are multistimuli responsive. The spectroscopic analysis revealed the partial formation of J‐aggregates both in the films and in powders, despite the weak luminescence. This behavior was interpreted as due to the partial formation of poorly fluorescent red‐shifted aggregates acting as a sink in an efficient excitation energy‐transfer process from J‐aggregates.