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How Inert are Osmium−Ligand Bonds? A Combined Thermal, Photochemical and Electrochemical Case Study With a Click Tripodal Ligand
Author(s) -
Klein Johannes,
Albold Uta,
Suntrup Lisa,
Sarkar Biprajit
Publication year - 2018
Publication title -
chemphotochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.13
H-Index - 18
ISSN - 2367-0932
DOI - 10.1002/cptc.201800008
Subject(s) - osmium , ligand (biochemistry) , chemistry , photochemistry , reactivity (psychology) , pyridine , electrochemistry , ruthenium , medicinal chemistry , organic chemistry , receptor , catalysis , medicine , biochemistry , alternative medicine , electrode , pathology
The first examples of osmium(II) complexes of the type [Os(L)(dmso)Cl] + (L=tripodal ligand) are reported. Photoactivation is shown to be a convenient route for performing ligand substitution reactions in such complexes. Photochemical bond activation works where thermal and electrochemical routes fail. Drastic differences are presented in the reactivity of the Os complexes with the pyridine‐containing ligands versus the triazole‐containing ligands. A detailed experimental and theoretical investigation into photochemical bond activation reactions is presented.