Photo‐Chromium: Sensitizer for Visible‐Light‐Induced Oxidative C−H Bond Functionalization—Electron or Energy Transfer? | Zendy

Otto Sven | Zendy; Nauth Alexander M. | Zendy; Ermilov Eugenyi | Zendy; Scholz Norman | Zendy; Friedrich Aleksej | Zendy; ReschGenger Ute | Zendy; Lochbrunner Stefan | Zendy; Opatz Till | Zendy; Heinze Katja | Zendy

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Photo‐Chromium: Sensitizer for Visible‐Light‐Induced Oxidative C−H Bond Functionalization—Electron or Energy Transfer?

Author(s) -

Otto Sven,

Nauth Alexander M.,

Ermilov Eugenyi,

Scholz Norman,

Friedrich Aleksej,

ReschGenger Ute,

Lochbrunner Stefan,

Opatz Till,

Heinze Katja

Publication year - 2017

Publication title -

chemphotochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.13

H-Index - 18

ISSN - 2367-0932

DOI - 10.1002/cptc.201700117

Subject(s) - intersystem crossing , photochemistry , singlet oxygen , photosensitizer , chemistry , intermolecular force , surface modification , electron transfer , singlet state , energy transfer , chromium , oxygen , molecule , excited state , organic chemistry , physics , nuclear physics , molecular physics

The front cover artwork is provided by a team of researchers from the Universities of Mainz and Rostock. The image shows the molecular structure of the Cr III photosensitizer [Cr(ddpd) 2 ] 3+ which enables C−H bond activation of tertiary amines through generation of singlet oxygen from air and light. Ultrafast intersystem crossing precludes intermolecular nonselective photoredox reactions and allows a selective photochemical pathway through singlet oxygen formation. Read the full text of the Communication at 10.1002/cptc.201700077.

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