Premium
A Family of Heterocyclic Naphthalene Diimide (NDI) Analogues: Comparing Parent Isoquinoline Diimides and Phthalazine Diimides with NDI
Author(s) -
Insuasty Alberto,
Carrara Serena,
Tang Linjing,
Forsyth Craig,
Hogan Conor F.,
McNeill Christopher R.,
Langford Steven J.
Publication year - 2019
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201900596
Subject(s) - chemistry , phthalazine , isoquinoline , diimide , naphthalene , photochemistry , quantum yield , electrochemistry , yield (engineering) , molecule , fluorescence , organic chemistry , perylene , physics , electrode , quantum mechanics , materials science , metallurgy
Parent isoquinoline diimide (IQDI) and phthalazine diimide (PTDI), as two new heterocyclic analogues of naphthalene diimides (NDIs), have been synthesized through an oxidative strategy in 35–79 % yield. X‐ray crystallography has been used to support the formation of IQDI, which also show fluorescence quantum yields of 3.5 %. The electrochemical and electrical properties of these molecules have been studied. The electrochemical results show an interesting trend in first reduction potential PTDI