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A Cobalt‐Modified Covalent Triazine‐Based Framework as an Efficient Cocatalyst for Visible‐Light‐Driven Photocatalytic CO 2 Reduction
Author(s) -
Bi Jinhong,
Xu Bin,
Sun Long,
Huang Huimin,
Fang Shengqiong,
Li Liuyi,
Wu Ling
Publication year - 2019
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201900329
Subject(s) - photocatalysis , triazine , cobalt , photochemistry , materials science , dielectric spectroscopy , visible spectrum , covalent bond , adsorption , catalysis , electron transfer , absorption spectroscopy , chemical engineering , chemistry , electrochemistry , organic chemistry , electrode , optoelectronics , polymer chemistry , optics , physics , engineering , metallurgy
Photocatalytic CO 2 reduction into carbonaceous feedstock chemicals is a promising renewable energy technology to convert solar energy and greenhouse gases into chemical fuels. Here, a covalent triazine‐based framework (CTF) is demonstrated as an efficient cocatalyst to reduce CO 2 under visible‐light irradiation. The nitrogen‐rich triazine moieties in CTF contribute to CO 2 adsorption, while the periodical pore structure of CTF favors the accommodation of CO 2 and electron mediator. Immobilization of cobalt species onto CTF promotes the photocatalytic activity with a 44‐fold enhancement over pristine CTF and the optimal CO production rate of the obtained Co/CTFs was up to 50 μmol g −1 h −1 . The results of solid‐state UV‐vis diffuse reflectance spectra (UV‐vis DRS), CO 2 adsorption and electrochemical impedance spectroscopy (EIS) illustrated that the increased activity was ascribed to the enhanced CO 2 capture capacity, improved absorption of visible‐light and facilitated the transfer of charge from CTF to CO 2 molecules. The CTF not only serves as a substrate for active Co species, but also bridges the photosensitizer with cobalt catalytic sites for the efficient transfer of photoexcited electrons. This work highlights the capability and ease of fabricating covalent organic framework‐based photocatalytic systems that are potentially useful for energy‐conversion applications.