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Visible‐Light‐Driven, One‐pot Amide Synthesis Catalyzed by the B 12 Model Complex under Aerobic Conditions
Author(s) -
Tian Hui,
Shimakoshi Hisashi,
Ono Toshikazu,
Hisaeda Yoshio
Publication year - 2019
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201800586
Subject(s) - amide , iridium , front cover , catalysis , derivative (finance) , chemistry , visible spectrum , combinatorial chemistry , cover (algebra) , stereochemistry , photochemistry , organic chemistry , materials science , optoelectronics , mechanical engineering , financial economics , engineering , economics
Invited for this month's cover is the group of Prof. Dr. Hisashi Shimakoshi at Kyushu University, Japan. The front cover shows “le mariage” of an iridium complex and a vitamin B 12 derivative with two wedding rings in the background. This collaboration of two complexes is induced by visible light in the presence of air to achieve green molecular transformations. This protocol was applied to the synthesis of amides from a wide range of trichlorinated organic compounds. Read the full text of the article at 10.1002/cplu.201800522 .