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Hydrolysis‐Initiated Domino Process on the Rim of Open‐Cage C 60 Derivatives Including Decarbonylation and Double Dehydration
Author(s) -
Zhang Hao,
Xu Liang,
Gan Liangbing
Publication year - 2017
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201700198
Subject(s) - decarbonylation , chemistry , hydroxylamine , oxime , aniline , hydrolysis , dehydration , derivative (finance) , cage , carbonyl group , domino , organic chemistry , medicinal chemistry , catalysis , biochemistry , mathematics , combinatorics , financial economics , economics
Hydrolysis of an open‐cage C 60 derivative in a mixture of HCl/AcOH/H 2 O resulted in removal of two hydroxyl groups, one carbonyl group and one aniline group in one step. A domino mechanism is proposed for the process. The newly formed open‐cage C 60 derivative has three carbonyl groups on the rim of the orifice, one of which could be converted into an oxime group by treatment with hydroxylamine.