N‐Phenylated N‐Heteroacenes: Synthesis, Structures, and Properties

Abstract Herein, two novel N‐phenylated N‐heteroacenes ( 1 and 2 ) are reported, along with details of their synthesis, structures, and properties. Compound 1 is a N‐hetero analogue of rubrene, but differs from rubrene by having a bent backbone and behaving as an insulator in the solid state owing to the lack of π–π interactions. Compound 2 is a N‐hetero analogue of 6,13‐diphenylpentacene (DPP) with essentially the same molecular geometry and crystal packing as DPP, but exhibiting a field effect mobility higher than that of DPP by two orders of magnitude.