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1,3‐Diaryl‐β‐diketone Organic Crystals with Red Amplified Spontaneous Emission
Author(s) -
Tang Baolei,
Zhang Houyu,
Cheng Xiao,
Ye Kaiqi,
Zhang Hongyu
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201600451
Subject(s) - fluorescence , quantum yield , photochemistry , conjugated system , solvent , molecule , chemistry , amplified spontaneous emission , laser , toluene , emission intensity , luminescence , polymer , tetraphenylporphyrin , diffusion , materials science , porphyrin , organic chemistry , optics , optoelectronics , physics , thermodynamics
In this study, 1‐[4‐(dimethylamino)phenyl]‐3‐(1‐hydroxynaphthalen‐2‐yl)propane‐1,3‐dione (DPHND) was designed and synthesized to construct red‐emissive organic solids. Although DPHND was weakly yellow fluorescent in organic solvents, its emission intensity showed a significant enhancement when a relatively large amount of poor solvent was added, and displayed typical aggregation‐induced enhanced emission (AIEE). Notably, the crystals formed by a solution‐diffusion approach showed bright red fluorescence ( λ em =621 nm), which was greatly redshifted by about 60 nm compared with that in solution. Molecules in crystals took a planar conformation and formed a herringbone packing structure, which effectively avoided π⋅⋅⋅π interactions, and hence contributed to the enhancement of the fluorescent quantum yield. The fluorescence spectrum of the long striplike crystals of DPHND gradually narrowed accompanied by a dramatic enhancement of the intensity when the pump energy of the laser beam was increased (355 nm), which indicated that these red‐emissive crystals displayed typical amplified spontaneous emission (ASE). In addition, DPHND with an extended π‐conjugated structure clearly improved its thermostability compared with the previously reported analogues, which may pave the way for its application in future electrically driven organic solid‐state lasers.