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Back Cover: Ordered Mesoporous Polyoxometalate–Organosilica Frameworks as Efficient Photocatalysts of the Hydrogen Evolution Reaction (ChemPlusChem 9/2016)
Author(s) -
Koutsouroubi Eirini D.,
Papadas Ioannis T.,
Armatas Gerasimos S.
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201600381
Subject(s) - polyoxometalate , silsesquioxane , photocatalysis , mesoporous material , lacunary function , materials science , catalysis , cover (algebra) , photochromism , porosity , polymer , hydrogen , chemical engineering , nanotechnology , photochemistry , chemistry , organic chemistry , mechanical engineering , mathematics , pure mathematics , engineering , composite material
The cover picture shows a porous polymeric framework composed of lacunary Keggin‐type [XM 11 O 39 ] q ‐ (X=P, Si; M=W, Mo) polyoxometalate clusters connected by ethane‐bridged silsesquioxane linkers. These new hybrid polymers present a relatively high photocatalytic activity for the hydrogen‐evolution reaction with remarkable cycle stability under UV/visible light irradiation ( λ >360 nm), without any co‐catalysts or additional photosensitizes. Details are given in the Full Paper by G. Armatas et al. on page 947 in Issue 9, 2016 (DOI: 10.1002/cplu.201600199).