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High Energy Density Materials Incorporating 4,5‐Bis(dinitromethyl)‐Furoxanate and 4,5‐Bis(dinitromethyl)‐3‐Oxy‐Furoxanate
Author(s) -
Zhai Lianjie,
Qu Xiaoni,
Wang Bozhou,
Bi Fuqiang,
Chen Sanping,
Fan Xuezhong,
Xie Gang,
Wei Qing,
Gao Shengli
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201600287
Subject(s) - furoxan , chemistry , detonation , energetic material , metal organic framework , salt (chemistry) , standard enthalpy of formation , metal , energy density , medicinal chemistry , combinatorial chemistry , organic chemistry , explosive material , nitric oxide , engineering physics , adsorption , engineering
3‐Oxy‐furoxanate is immobilized in a heterometallic energetic metal–organic framework (MOFs). Two furoxan‐based MOFs ([Ag 2 K 4 (BDOFO)(BDFO) 2 (H 2 O) 6 ] n , [K 2 (BDFO)] n ) and a salt ([(BDFO 2− )(NH 2 NH 3 + ) 2 (H 2 O)] n (BDOFO 2− =4,5‐bis(dinitromethyl)‐3‐oxy‐furoxanate, BDFO 2− =4,5‐bis(dinitromethyl)‐furoxanate) are synthesized and their energetic performance evaluated. This study outlines the systematic investigation of detonation performance of 3‐oxy‐furoxan and its derivatives.