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Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State
Author(s) -
Elacqua Elizabeth,
Sinnwell Michael A.,
Loren Bradley P.,
Jurgens Paul T.,
Groeneman Ryan H.,
Reinheimer Eric W.,
MacGillivray Leonard R.
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201600261
Subject(s) - chemistry , solid state , yield (engineering) , hydrogen bond , template , metal , coordination complex , carbon fibers , hydrogen , double bond , organic chemistry , polymer chemistry , photochemistry , molecule , materials science , nanotechnology , metallurgy , composite material , composite number
Abstract Trisubstituted olefins are reactants in template‐directed, solid‐state [2+2] photocycloaddition reactions. Whereas hydrogen‐bond‐based templates afford crystalline assemblies with olefins that are photostable, Ag I coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.