Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State | Zendy

Elacqua Elizabeth | Zendy; Sinnwell Michael A. | Zendy; Loren Bradley P. | Zendy; Jurgens Paul T. | Zendy; Groeneman Ryan H. | Zendy; Reinheimer Eric W. | Zendy; MacGillivray Leonard R. | Zendy

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Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State

Author(s) -

Elacqua Elizabeth,

Sinnwell Michael A.,

Loren Bradley P.,

Jurgens Paul T.,

Groeneman Ryan H.,

Reinheimer Eric W.,

MacGillivray Leonard R.

Publication year - 2016

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201600261

Subject(s) - chemistry , solid state , yield (engineering) , hydrogen bond , template , metal , coordination complex , carbon fibers , hydrogen , double bond , organic chemistry , polymer chemistry , photochemistry , molecule , materials science , nanotechnology , metallurgy , composite material , composite number

Trisubstituted olefins are reactants in template‐directed, solid‐state [2+2] photocycloaddition reactions. Whereas hydrogen‐bond‐based templates afford crystalline assemblies with olefins that are photostable, Ag I coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.

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