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A Highly Sensitive Luminescent Dye@MOF Composite for Probing Different Volatile Organic Compounds
Author(s) -
Zheng JunPing,
Ou Sha,
Zhao Min,
Wu ChuanDe
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201600057
Subject(s) - luminescence , moiety , materials science , fluorescence , metal organic framework , photochemistry , molecule , composite number , chemistry , organic chemistry , optoelectronics , physics , adsorption , quantum mechanics , composite material
Abstract The probing of volatile organic compounds (VOCs) is critical and challenging in biotechnology and environmental monitoring. Incorporation of luminescent moieties into metal–organic frameworks (MOFs) has produced many unique luminescent sensors for probing different VOCs. The emissions of most MOF sensors are based mainly on the single transitions of luminescent moieties, so the luminescence readouts are only predominant for some special VOCs. We use a natural amino acid derivative as the luminescent moiety to result in a lamellar coordination polymer, and further embed luminescent dye molecules in the crystal matrix to result in a luminescent dye@MOF sensor. The composite sensor exhibits excellent sensitivity for decoding different VOCs with clearly differentiable fluorescence emission by tuning the energy transfer efficiency from the organic ligand to the dye moieties. The composite luminescent sensor is self‐calibrated, and much more stable and instantaneous than other more widely explored luminescent sensors.