Synthesis, Structure, and Ligand‐Centered Catalytic Properties of M II  Coordination Polymers (M=Zn II , Cd II , Hg II ) with Open Pyridyl  N ‐Oxide Sites | Zendy

Cheng JunYan | Zendy; Ding FengWen | Zendy; Wang Peng | Zendy; Zhao ChaoWei | Zendy; Dong YuBin | Zendy

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Synthesis, Structure, and Ligand‐Centered Catalytic Properties of M II Coordination Polymers (M=Zn II , Cd II , Hg II ) with Open Pyridyl N ‐Oxide Sites

Author(s) -

Cheng JunYan,

Ding FengWen,

Wang Peng,

Zhao ChaoWei,

Dong YuBin

Publication year - 2016

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201600009

Subject(s) - ligand (biochemistry) , catalysis , chemistry , coordination complex , crystallography , zinc , inorganic chemistry , stereochemistry , metal , organic chemistry , receptor , biochemistry

Four M II (M=Zn II , Cd II , Hg II ) coordination polymers were designed and synthesized based on two pyridine N ‐oxide bridging ligands: 3,5‐bis(4‐pyridyl)pyridine N ‐oxide and 2,6‐bis(3‐pyridyl)pyridine N ‐oxide. The resulting polymers all feature a one‐dimensional chain motif and contain free pyridyl moieties. More importantly, they exhibit interesting ligand‐centered (pyridyl N ‐oxide) catalytic behavior, and can be used as highly heterogeneous catalysts to promote the Knoevenagel condensation reaction under ambient conditions.

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