Electrocatalytic Reduction of Carbon Dioxide with a Well‐Defined PN 3 −Ru Pincer Complex | Zendy

Min Shixiong | Zendy; Rasul Shahid | Zendy; Li Huaifeng | Zendy; Grills David C. | Zendy; Takanabe Kazuhiro | Zendy; Li LainJong | Zendy; Huang KuoWei | Zendy

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Electrocatalytic Reduction of Carbon Dioxide with a Well‐Defined PN 3 −Ru Pincer Complex

Author(s) -

Min Shixiong,

Rasul Shahid,

Li Huaifeng,

Grills David C.,

Takanabe Kazuhiro,

Li LainJong,

Huang KuoWei

Publication year - 2016

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201500474

Subject(s) - pincer movement , electrocatalyst , chemistry , redox , ligand (biochemistry) , pincer ligand , electrochemical reduction of carbon dioxide , carbon dioxide , reduction (mathematics) , carbon fibers , inorganic chemistry , bipyridine , electrochemistry , medicinal chemistry , photochemistry , catalysis , carbon monoxide , materials science , crystallography , organic chemistry , electrode , receptor , biochemistry , geometry , mathematics , composite material , composite number , crystal structure

A well‐defined PN 3 −Ru pincer complex ( 5 ) bearing a redox‐active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO 2 reduction to CO and HCOOH with negligible formation of H 2 in a H 2 O/MeCN mixture.

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