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Study of Multiporphyrin Compounds as Colorimetric Sitting‐Atop Metal Complexes: Synthesis and Photophysical Studies
Author(s) -
Costa Joana I. T.,
Oliveira Elisabete,
Santos Hugo M.,
Tomé Augusto C.,
Neves Maria G. P. M. S.,
Lodeiro Carlos
Publication year - 2016
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201500386
Subject(s) - metal , chemistry , photochemistry , combinatorial chemistry , nanotechnology , materials science , organic chemistry
Abstract Mono‐, di‐, tri‐, and hexaporphyrin derivatives were synthesized and their sensorial ability toward Na + , Li + , Ca 2+ , Cu 2+ , Ni 2+ , Co 2+ , Fe 3+ , Zn 2+ , Cd 2+ , Hg 2+ , Ag + , Cr 3+ , Pb 2+ , and Al 3+ was explored by absorption and emission spectroscopy and 1 H NMR spectroscopy. For all of the studied porphyrin derivatives the most significant spectral changes were observed upon addition of Zn 2+ , Cd 2+ , Cu 2+ , Co 2+ , Pb 2+ , Hg 2+ , and Fe 3+ , which resulted in a color change from red to green. When the remaining metal ions were tested, no significant changes were observed. The results reveal, as expected, the formation of mononuclear complexes for porphyrin 4 , dinuclear complexes for diporphyrin 7 , and trinuclear complexes for triporphyrins 9 and 10 . In addition, complexes of type M 6 L were determined for hexaporphyrin 8 . The NMR spectroscopy studies suggest that the interaction with the metals occurs with the formation of sitting‐atop complexes. This study also shows that the sensitivity increases with increasing number of coordination sites, with the most pronounced case observed for Hg 2+ . The lowest value of detectable concentration of 0.05 μ m for Hg 2+ was achieved for hexaporphyrin 8 .