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Interfacial Synthesis of Electrically Conducting Palladium Bis(dithiolene) Complex Nanosheet
Author(s) -
Pal Tigmansu,
Kambe Tetsuya,
Kusamoto Tetsuro,
Foo Maw Lin,
Matsuoka Ryota,
Sakamoto Ryota,
Nishihara Hiroshi
Publication year - 2015
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201500206
Subject(s) - chemistry , palladium , nanosheet , metal , selected area diffraction , ligand (biochemistry) , nickel , phase (matter) , crystallography , inorganic chemistry , polymer chemistry , nanotechnology , transmission electron microscopy , catalysis , organic chemistry , materials science , biochemistry , receptor
The synthesis of palladium bis(dithiolene) complex nanosheets (PdDt) possessing a kagome‐type lattice structure was performed via interfacial reaction between metal salt in aqueous phase and dithiolato ligand in organic phase. The PdDt nanosheets were characterised by AFM, STM, TEM revealing flat and sheet‐like morphology; IR, UV spectroscopy show the corresponding coordination connectivity between metal and ligand, followed by powder X‐ray diffraction and SAED, which determined nanosheets to be structurally similar to previously reported nickel bis(dithiolene) complex nanosheets NiDt.