Premium
A Triazolyl‐Pyridine‐Supported Cu I Dimer: Tunable Luminescence and Fabrication of Composite Fibers
Author(s) -
Bai ShiQiang,
Kai Dan,
Ke Karen Lin,
Lin Ming,
Jiang Lu,
Jiang Ying,
Young David James,
Loh Xian Jun,
Li Xu,
Hor T. S. Andy
Publication year - 2015
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201500202
Subject(s) - luminescence , chemistry , thermogravimetric analysis , photoluminescence , benzonitrile , composite number , iodide , pyridine , dimer , fabrication , copper , polymer chemistry , crystallography , nuclear chemistry , inorganic chemistry , optoelectronics , organic chemistry , materials science , composite material , medicine , alternative medicine , pathology
The dinuclear complex [Cu 2 I 2 (L1) 2 ] ( 1 ) (L1=3‐((4‐(pyridin‐2‐yl)‐1 H ‐1,2,3‐triazol‐1‐yl)methyl)benzonitrile) is characterized by single‐crystal X‐ray diffraction (XRD), powder XRD, IR, photoluminescence spectroscopy, and thermogravimetric analysis. Unlike other related, known copper iodide complexes, it exhibits strong yellow emission in the solid state at both room temperature and 77 K. Showing good compatibility with PMMA, it is blended with the polymer in different weight ratios to prepare luminescent composite fibers.