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A Facile and One‐Step Synthesis of Visible‐Light‐Responsive Silver and Mesoporous Carbon Comodified Carbon–Zinc Oxide Composites
Author(s) -
Wang Fangxiao,
Liang Lin,
Shi Lei,
Liu Mengshuai,
Sun Jianmin
Publication year - 2015
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201500158
Subject(s) - rhodamine b , photocatalysis , materials science , mesoporous material , visible spectrum , carbon fibers , adsorption , zinc , chemical engineering , catalysis , oxide , composite number , composite material , chemistry , organic chemistry , metallurgy , optoelectronics , engineering
Silver and mesoporous carbon (mC) comodified CZnO composites (Ag/mC/CZnO) were fabricated by a facile, one‐step process directly from C, Ag, and Zn precursors in CO 2 ‐expanded ethanol, which provided a unique medium and did not require additional precipitant and mesoscaled organic templates. When the composite photocatalyst was applied to the degradation of rhodamine B and phenol, Ag/mC/CZnO exhibited excellent photocatalytic activity in visible light. The remarkably improved catalytic activity of the composites was attributed to the following synergistic effects. The modification of mC enriched the adsorption of pollutants on the photocatalyst. Additionally, the mesopores of carbon provided a spacious path for the separation of photogenerated electrons and holes. In addition to mC, carbon was also doped into ZnO, which narrowed the ZnO band gap. The modification of silver strengthened the absorbance of the visible region and improved the electron‐trapping ability.