Comparative Analysis of the Olfactory Properties of Silicon/Germanium/Tin Analogues of the Lily‐of‐the‐Valley Odorants Lilial and Bourgeonal | Zendy

Dörrich Steffen | Zendy; Gelis Lian | Zendy; Wolf Steffen | Zendy; Sunderkötter Astrid | Zendy; Mahler Christoph | Zendy; Guschina Elena | Zendy; Tacke Reinhold | Zendy; Hatt Hanns | Zendy; Kraft Philip | Zendy

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Comparative Analysis of the Olfactory Properties of Silicon/Germanium/Tin Analogues of the Lily‐of‐the‐Valley Odorants Lilial and Bourgeonal

Author(s) -

Dörrich Steffen,

Gelis Lian,

Wolf Steffen,

Sunderkötter Astrid,

Mahler Christoph,

Guschina Elena,

Tacke Reinhold,

Hatt Hanns,

Kraft Philip

Publication year - 2014

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201402160

Subject(s) - tin , germanium , chemistry , silicon , stereochemistry , odor , receptor , biochemistry , organic chemistry

The silicon/germanium/tin analogues of the lily‐of‐the‐valley odorants lilial ( rac ‐ 1 a ), compounds rac ‐ 1 b , rac ‐ 1 c , and rac ‐ 1 d , and bourgeonal ( 2 a ), compounds 2 b , 2 c , and 2 d , were synthesized and characterized for their olfactory properties, including GC–olfactometry studies. Compounds rac ‐ 1 a – c and 2 a – c possess a typical lily‐of‐the‐valley odor, whereas the stanna‐analogues rac ‐ 1 d and 2 d , despite some floral aspects, clearly no longer belong to the lily‐of‐the‐valley family. In both series of the carbon/silicon/germanium/tin analogues studied, the lily‐of‐the‐valley odor decreases in the order of carbon

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