Premium
A Microsized Cagelike Sulfur/Carbon Composite for a Lithium/Sulfur Battery with Excellent Performance
Author(s) -
Wang Meiri,
Zhang Yining,
Zhang Hongzhang,
Zhang Huamin
Publication year - 2014
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201402021
Subject(s) - polysulfide , sulfur , composite number , materials science , battery (electricity) , carbon fibers , chemical engineering , electrode , redistribution (election) , porosity , lithium–sulfur battery , electron transfer , ion , nanotechnology , electrochemistry , chemistry , composite material , organic chemistry , electrolyte , metallurgy , power (physics) , physics , quantum mechanics , politics , political science , law , engineering
A sulfur/carbon composite with a hollow cagelike configuration is synthesized and employed as a lithium/sulfur battery. The material provides a hierarchical porous structure with small pores in local regions and large pores connected to each other throughout the electrode. It exhibits a good polysulfide retention ability, promotes the efficient transfer of electrons and ions, and suppresses the redistribution of active material during cycles. Thus, the battery shows an improved rate performance, as well as a superior cycling stability of 94 % capacity retention, after 100 cycles at 0.5 C.