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Cover Picture: Direct Selective Hydrogenation of Phenol and Derivatives over Polyaniline‐Functionalized Carbon‐Nanotube‐Supported Palladium (ChemPlusChem 2/2013)
Author(s) -
Chen Jinzhu,
Zhang Wei,
Chen Limin,
Ma Longlong,
Gao Hui,
Wang Tiejun
Publication year - 2013
Publication title -
chempluschem
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201390006
Subject(s) - cyclohexanone , palladium , polyaniline , phenol , bifunctional , selectivity , catalysis , carbon nanotube , materials science , chemistry , chemical engineering , organic chemistry , nanotechnology , polymer , polymerization , engineering
The cover picture shows a catalyst, made of palladium nanoparticles supported on polyaniline‐functionalized carbon nanotubes (Pd–PANI/CNT), that is highly active towards the direct hydrogenation of phenol to cyclohexanone. Phenol conversion exceeding 99% was achieved with a cyclohexanone selectivity of >99% under atmospheric pressure of hydrogen in aqueous media. In their Full Paper on page 142 ff. Jinzhu Chen and co‐workers report on a bifunctional stabilizing mechanism of the composite support PANI/CNT on palladium nanoparticles in the catalyst Pd‐PANI/CNT, and how the PANI/CNT can play a role in controlling the conversion and selectivity in the direct hydrogenation of phenol to cyclohexanone.
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