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A Facile, Template‐Free Synthesis of AgCl Hierarchical Architectures: Precursors of Highly Efficient Visible‐Light Plasmonic Photocatalysts of Ag@AgCl
Author(s) -
Wang Yu,
Chen Gang,
Di Andi,
Xu Haiming
Publication year - 2014
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201300420
Subject(s) - photocatalysis , methyl orange , visible spectrum , photodegradation , materials science , x ray photoelectron spectroscopy , nanostructure , plasmon , diffuse reflectance infrared fourier transform , photochemistry , chemical engineering , spectroscopy , nanotechnology , catalysis , optoelectronics , chemistry , organic chemistry , physics , quantum mechanics , engineering
This paper describes a facile, template‐free synthesis of AgCl hierarchical structures by a gas–liquid interfacial method and the morphology of AgCl (microrods or film) can be conveniently varied or controlled by changing the solvents of AgNO 3 without using any surfactants. The AgCl composites were then photoreduced to form highly efficient visible‐light plasmonic photocatalyst Ag@AgCl nanostructures. SEM, XRD, X‐ray photoelectron spectroscopy, and UV/Vis diffuse reflectance spectroscopy were used to characterize the obtained product. The photocatalytic activity of the obtained product was evaluated by the photodegradation of methyl orange pollutant under visible‐light irradiation, and it was found that Ag@AgCl microrods exhibited high visible‐light photocatalytic activity and good stability.

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