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Dual Lewis Base Functionalization of Ionic Liquids for Highly Efficient and Selective Capture of H 2 S
Author(s) -
Huang Kuan,
Cai DaNiu,
Chen YongLe,
Wu YouTing,
Hu XingBang,
Zhang ZhiBing
Publication year - 2014
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201300365
Subject(s) - ionic liquid , selectivity , chemistry , amine gas treating , lewis acids and bases , surface modification , absorption (acoustics) , base (topology) , ionic bonding , organic chemistry , materials science , ion , catalysis , mathematical analysis , mathematics , composite material
Three dual Lewis base functionalized ionic liquids (DLB‐ILs) tethered with both carboxyl and tertiary amine groups on their anions were designed for highly efficient and selective absorption of H 2 S. It was found that the DLB‐ILs could reversibly absorb 0.39–0.84 mol of H 2 S per mole of IL at 1 bar and 60 °C, which is significantly higher than that of other ILs. On the contrary, the CO 2 absorption in this class of DLB‐ILs was shown to be quite limited relative to H 2 S owing to the coupling effect of the two Lewis base groups. It is the dual Lewis base functionalization that enables the significantly high values calculated for the ideal absorption selectivity for H 2 S/CO 2 , that is, 13–26 at 1 bar and 29–70 at 0.1 bar (60 °C). The selectivity even goes up to >100 at low pressures and high temperatures. It was further illustrated from DFT calculations and spectroscopy studies that the cooperation interaction of carboxyl ⋅⋅⋅ H 2 S ⋅⋅⋅ amine and the reduced binding with CO 2 were the major contributions to the high H 2 S absorption capacity and H 2 S/CO 2 selectivity.