Synthesis of Zeolitic Imidazolate Framework‐7 in a Water/Ethanol Mixture and Its Ethanol‐Induced Reversible Phase Transition | Zendy

He Ming | Zendy; Yao Jianfeng | Zendy; Li Lunxi | Zendy; Wang Kun | Zendy; Chen Fanyan | Zendy; Wang Huanting | Zendy

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Synthesis of Zeolitic Imidazolate Framework‐7 in a Water/Ethanol Mixture and Its Ethanol‐Induced Reversible Phase Transition

Author(s) -

He Ming,

Yao Jianfeng,

Li Lunxi,

Wang Kun,

Chen Fanyan,

Wang Huanting

Publication year - 2013

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201300193

Subject(s) - zeolitic imidazolate framework , ethanol , phase (matter) , imidazolate , chemical engineering , chemistry , phase transition , inorganic chemistry , materials science , adsorption , organic chemistry , metal organic framework , thermodynamics , physics , engineering

Room to breathe : An efficient method for the synthesis of zeolitic imidazolate framework‐7 (ZIF‐7) in ethanol/water at room temperature is reported. The ZIF‐7 undergoes a reverse‐phase transition from large pore (lp)‐phase to narrow pore (np)‐phase under heat treatment and from np‐phase back to lp‐phase in ethanol solution.

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