Self‐Assembly and Visible‐Light Photocatalytic Properties of W/Nb Mixed‐Addendum Polyoxometalate and Transition‐Metal Cations | Zendy

Huang Peng | Zendy; Qin Chao | Zendy; Wang XinLong | Zendy; Sun ChunYi | Zendy; Jiao YanQing | Zendy; Xing Yan | Zendy; Su ZhongMin | Zendy; Shao KuiZhan | Zendy

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Self‐Assembly and Visible‐Light Photocatalytic Properties of W/Nb Mixed‐Addendum Polyoxometalate and Transition‐Metal Cations

Author(s) -

Huang Peng,

Qin Chao,

Wang XinLong,

Sun ChunYi,

Jiao YanQing,

Xing Yan,

Su ZhongMin,

Shao KuiZhan

Publication year - 2013

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201300175

Subject(s) - addendum , polyoxometalate , photocatalysis , triethylamine , transition metal , visible spectrum , aqueous solution , cluster (spacecraft) , nanotechnology , chemistry , materials science , photochemistry , computer science , catalysis , organic chemistry , optoelectronics , political science , law , programming language

Making light work : Three novel W/Nb mixed‐addendum polyoxometalates, which all contain the {SiNb 3 W 9 O 40 } cluster, have been synthesized by conventional aqueous methods. Visible‐light photocatalytic H 2 evolution activity (see figure) was observed for two of the compounds, with H 2 PtCl 6 as a cocatalyst and triethylamine as a sacrificial electron donor.

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