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Pentakis(trifluoromethyl)benzenediazonium Cation: A Useful Building Block for the Syntheis of Trifluoromethyl‐Substituted Derivatives
Author(s) -
Kütt Agnes,
Werner Franz,
Kaljurand Ivari,
Leito Ivo,
Koppel Ilmar A.
Publication year - 2013
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201300160
Subject(s) - trifluoromethyl , yield (engineering) , steric effects , salt (chemistry) , information storage , chemistry , block (permutation group theory) , combinatorial chemistry , computer science , organic chemistry , database , mathematics , materials science , combinatorics , alkyl , metallurgy
The sterically crowded , highly electron‐deficient diazonium salt C 6 (CF 3 ) 5 N 2 + BF 4 − has been synthesized and sample dediazotization reactions were carried out. New compounds, C 6 (CF 3 ) 5 I, C 6 (CF 3 ) 5 NO 2 , and C 6 (CF 3 ) 5 NO were isolated and identified. Also, a more convenient route to C 6 (CF 3 ) 5 NH 2 that gave good yield was achieved.