COK‐16: A Cation‐Exchanging Metal–Organic Framework Hybrid | Zendy

Bajpe Sneha R. | Zendy; Breynaert Eric | Zendy; MartinCalvo Ana | Zendy; Mustafa Danilo | Zendy; Calero Sofia | Zendy; Kirschhock Christine E. A. | Zendy; Martens Johan A. | Zendy

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COK‐16: A Cation‐Exchanging Metal–Organic Framework Hybrid

Author(s) -

Bajpe Sneha R.,

Breynaert Eric,

MartinCalvo Ana,

Mustafa Danilo,

Calero Sofia,

Kirschhock Christine E. A.,

Martens Johan A.

Publication year - 2013

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201300080

Subject(s) - polyoxometalate , porosity , ion exchange , metal organic framework , metal , spectroscopy , ion , chemistry , inorganic chemistry , charge exchange , metal ions in aqueous solution , hybrid material , irradiation , materials science , catalysis , organic chemistry , physics , adsorption , quantum mechanics , nuclear physics

X‐ray spectroscopy : Substoichiometric encapsulation of polyoxometalate ions into a metal–organic framework results in a fully functional cation exchanger with accessible porosity. Cu 2+ cations compensating the charge of [PW 12 O 40 ] 3− in the as‐synthesized material can be exchanged with cations such as Na + and Eu 3+ . When exchanged with Eu 3+ , the material appears bright red under UV irradiation (see figure).

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