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Radical‐Functionalised Gel: A Building‐Block Strategy for Magnetochiral Assembly
Author(s) -
Mannini Matteo,
Cicchi Stefano,
Berti Debora,
Caneschi Andrea,
Brandi Alberto,
Lascialfari Luisa,
Sorace Lorenzo
Publication year - 2013
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201200250
Subject(s) - supramolecular chemistry , paramagnetism , materials science , nanotechnology , chemical engineering , scaffold , spectroscopy , self assembly , chemistry , polymer chemistry , organic chemistry , molecule , computer science , physics , quantum mechanics , engineering , database
A chiral organogelating scaffold is functionalised with a stable organic radical pendant. The morphology and spectroscopic properties of the gels are investigated as a function of the organogelator concentration and temperature. The combination of AFM and ESR spectroscopy provides firm evidence that the architecture responsible for the formation of the macroscopic gel (i.e., the fibrillar structure) is maintained below the gelling concentration. This opens relevant perspectives in terms of the realisation of complex supramolecular chiral structures incorporating paramagnetic functions, and demonstrates that the ESR technique is suitable as a fast and direct check of the sample state (gel, solution, or small aggregates).