A Family of Discrete Magnetically Switchable Nanoballs | Zendy

Duriska Martin B. | Zendy; Neville Suzanne M. | Zendy; Moubaraki Boujemaa | Zendy; Murray Keith S. | Zendy; Balde Chérif | Zendy; Létard JeanFrançois | Zendy; Kepert Cameron J. | Zendy; Batten Stuart R. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Family of Discrete Magnetically Switchable Nanoballs

Author(s) -

Duriska Martin B.,

Neville Suzanne M.,

Moubaraki Boujemaa,

Murray Keith S.,

Balde Chérif,

Létard JeanFrançois,

Kepert Cameron J.,

Batten Stuart R.

Publication year - 2012

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201200123

Subject(s) - thiocyanate , spin crossover , excited state , crystallography , materials science , chemistry , atomic physics , inorganic chemistry , physics

The thermal and light‐induced magnetic properties of a family of discrete magnetically switchable “nanoball” species (3 nm in diameter) is reported. The self‐assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp 4‐py ])(NCCH 3 )] ([Tp 4‐py ]=tris‐[3‐(4'‐pyridyl)pyrazol‐1‐yl]hydroborate), combined with a [Fe(NCX) 2 ] (X=S, Se and BH 3 ) species. We previously showed that the thiocyanate analogue ( Fe(NCS)‐nano ) undergoes a thermal and light‐induced spin crossover (SCO)—the largest such discrete SCO material reported. Now included in this family are the Se and BH 3 analogues, Fe(NCSe)‐nano and Fe(NCBH 3 )‐nano , which show increased thermal transition temperatures ( T 1/2 =124 K, 162 and 173 K). This variation in transition temperature over the series S

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research