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Honeycomb Porous Framework of Zinc(II): Effective Host for Palladium Nanoparticles for Efficient Three‐Component (A 3 ) Coupling and Selective Gas Storage
Author(s) -
Jayaramulu Kolleboyina,
Datta Kasibhatta K. R.,
Suresh Mothika V.,
Kumari Gayatri,
Datta Ranjan,
Narayana Chandrabhas,
Eswaramoorthy Muthusamy,
Maji Tapas Kumar
Publication year - 2012
Publication title -
chempluschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.801
H-Index - 61
ISSN - 2192-6506
DOI - 10.1002/cplu.201200093
Subject(s) - palladium , zinc , nanoparticle , stabilizer (aeronautics) , component (thermodynamics) , porosity , catalysis , combinatorial chemistry , chemistry , porous medium , coupling (piping) , host (biology) , materials science , chemical engineering , nanotechnology , organic chemistry , physics , engineering , ecology , biology , thermodynamics , metallurgy , mechanical engineering
MOF for effective stabilizer for “Pd” and selective host for CO 2 : A porous, layered MOF system {[Zn(Himdc)(bipy)].DMF} ( 1 ; Himdc=4,5‐imidazoledicarboxylate, bipy=4,4'‐bipyridine) shows selective gas‐storage properties, while the polar nanochannels serve as functional scaffold for the stabilization of highly dispersed Pd nanoparticles. The Pd@MOF1 a hybrid is a highly active and recyclable catalyst for the synthesis of propargylamine derivatives through A 3 coupling reactions.