Synthesis and Stabilisation of MgH 2  Nanoparticles by Self‐Assembly | Zendy

AgueyZinsou KondoFrancois | Zendy; Boyer Cyrille | Zendy

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Synthesis and Stabilisation of MgH 2 Nanoparticles by Self‐Assembly

Author(s) -

AgueyZinsou KondoFrancois,

Boyer Cyrille

Publication year - 2012

Publication title -

chempluschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.801

H-Index - 61

ISSN - 2192-6506

DOI - 10.1002/cplu.201200027

Subject(s) - nanoparticle , nucleation , magnesium , nanotechnology , azide , materials science , thermal stability , scalability , computer science , chemistry , database , organic chemistry , metallurgy

A simple and scalable method for the synthesis and stabilisation of MgH 2 nanoparticles by self‐assembly and confinement has been developed. An azide‐terminated poly(styrene; PSTN) with good thermal stability provided a nucleation point for anchoring the polymer at the magnesium surface (see scheme). The hybrid PSTN/MgH 2 nanotubes maintain relatively fast kinetics and retaining a third of the theoretical hydrogen storage capacity of magnesium.

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