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The Drude‐Smith Equation and Related Equations for the Frequency‐Dependent Electrical Conductivity of Materials: Insight from a Memory Function Formalism
Author(s) -
Chen WeiChen,
Marcus Rudolph A.
Publication year - 2021
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.202100299
Subject(s) - drude model , formalism (music) , scattering , physics , statistical physics , kubo formula , conductivity , quantum mechanics , theoretical physics , art , musical , visual arts
The Drude‐Smith equation is widely used for treating the frequency‐dependent electrical conductivity of materials in the terahertz region. An attractive feature is its sparsity of adjustable parameters. A significant improvement over Drude theory for these materials, the theory includes backscattering of the charge carriers. It has nevertheless been criticized, including by Smith himself, because of the arbitrariness of a step in the derivation. We recall a somewhat similar behavior of back scattering in fluids observed in molecular dynamics computations and discussed in terms of memory functions. We show how theories such as Drude‐Smith and Cocker et al . are examples of a broader class of theories by showing how they also arise as particular cases of a memory function formalism that divides the interactions into short and long range.