In‐Situ Growth of Gadolinium Phthalocyaninato Sandwich Complexes on the Ag(111) Surface | Zendy

Urgel José I. | Zendy; Écija David | Zendy; Vijayaraghavan Saranyan | Zendy; Pörtner Mathias | Zendy; Bocquet MarieLaure | Zendy; Auwärter Willi | Zendy; Barth Johannes V. | Zendy

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In‐Situ Growth of Gadolinium Phthalocyaninato Sandwich Complexes on the Ag(111) Surface

Author(s) -

Urgel José I.,

Écija David,

Vijayaraghavan Saranyan,

Pörtner Mathias,

Bocquet MarieLaure,

Auwärter Willi,

Barth Johannes V.

Publication year - 2019

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201900253

Subject(s) - gadolinium , scanning tunneling microscope , stoichiometry , in situ , substrate (aquarium) , deposition (geology) , chemistry , materials science , crystallography , nanoclusters , analytical chemistry (journal) , nanotechnology , organic chemistry , paleontology , oceanography , sediment , geology , biology

We report a low‐temperature scanning tunneling microscopy investigation of the in‐situ growth of gadolinium phthalocyaninato complexes by combined deposition of free‐base phthalocyanines and gadolinium atoms on a smooth Ag(111) substrate. A careful control of the stoichiometry allows the expression of a multilevel structurecomposed of irregularly distributed Gd x ‐1 (Pc) x complexes, x =2–5, thus paving new avenues for surface‐confined columnar growth.

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