Front Cover: Electrochemical Formation of Fe(IV)=O Derived from H 2 O 2  on a Hematite Electrode as an Active Catalytic Site for Selective Hydrocarbon Oxidation Reactions (ChemPhysChem 5/2019) | Zendy

Kamiya Kazuhide | Zendy; Kuwabara Akito | Zendy; Harada Takashi | Zendy; Nakanishi Shuji | Zendy

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Front Cover: Electrochemical Formation of Fe(IV)=O Derived from H 2 O 2 on a Hematite Electrode as an Active Catalytic Site for Selective Hydrocarbon Oxidation Reactions (ChemPhysChem 5/2019)

Author(s) -

Kamiya Kazuhide,

Kuwabara Akito,

Harada Takashi,

Nakanishi Shuji

Publication year - 2019

Publication title -

chemphyschem

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201900160

Subject(s) - hematite , chemistry , overpotential , hydrocarbon , catalysis , inorganic chemistry , front cover , electrode , electrochemistry , active site , mineralogy , cover (algebra) , organic chemistry , mechanical engineering , engineering

The Front Cover shows that Fe(lV)=O is generated by the oxidative decomposition of H 2 O 2 on a hematite electrode and serves as the active center for selective styrene epoxidation. The generation of Fe(IV)=O from H 2 O 2 exhibited lower overpotential than that from H 2 O. This work is the first demonstration that Fe(IV)=O on a hematite electrode is applied to hydrocarbon oxidation reactions. More information can be found in the Communication by K. Kamiya et al. on page 648 in Issue 5, 2019 (DOI: 10.1002/cphc.201801207).

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