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Interactions of Hydrogen with Pd@MOF Composites
Author(s) -
Malouche Abdelmalek,
Zlotea Claudia,
Szilágyi Petra Ágota
Publication year - 2019
Publication title -
chemphyschem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.016
H-Index - 140
eISSN - 1439-7641
pISSN - 1439-4235
DOI - 10.1002/cphc.201801092
Subject(s) - physisorption , nanoclusters , sorption , chemisorption , hydrogen storage , metal organic framework , nanocomposite , hydrogen , palladium , materials science , composite number , nanoparticle , chemical engineering , metal , nanotechnology , composite material , adsorption , chemistry , alloy , catalysis , organic chemistry , metallurgy , engineering
Physisorption and chemisorption of hydrogen on solid‐state materials are two fundamentally different interactions, both of which display advantages and drawbacks for hydrogen storage. It has been hypothesised that their combination by merging two classes of materials showing different sorption behaviour towards hydrogen in the same composite may synergistically combine their desirable properties. As representatives of such composites, palladium nanoparticles, nanoclusters, and single atoms have been encapsulated in a metal‐organic framework matrix, embedded, or immobilised in its pores, respectively. In this minireview, we review advances on the understanding and potential applications of the combination of Pd with metal‐organic framework matrices through the analysis of the nanocomposite materials’ interaction with hydrogen and sorption properties.