Thermochemical Insights into Fullerene Aggregation and the Phthalocyanine–Fullerene Interaction in Efficient Solvents | Zendy

Lebedeva Nathalya S. | Zendy; Gubarev Yuri A. | Zendy; Kolker Arkadiy M. | Zendy; Borovkov Nicholas Y. | Zendy

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Thermochemical Insights into Fullerene Aggregation and the Phthalocyanine–Fullerene Interaction in Efficient Solvents

Author(s) -

Lebedeva Nathalya S.,

Gubarev Yuri A.,

Kolker Arkadiy M.,

Borovkov Nicholas Y.

Publication year - 2018

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201701127

Subject(s) - fullerene , isothermal titration calorimetry , chemistry , solvent , phthalocyanine , non covalent interactions , colloid , spectroscopy , solvent effects , hydrocarbon , molecule , organic chemistry , hydrogen bond , physics , quantum mechanics

The physicochemical behavior of fullerene C 60 in hydrocarbon solvents is examined by isothermal titration calorimetry, photocalorimetry, and UV spectroscopy. The obtained data are summarized to substantiate the idea of the binary fullerene/solvent cluster as a colloidal nanoentity that moderates noncovalent interactions of the C 60 molecule in solution. This idea serves to aid understanding of the complex physicochemical behavior of tert ‐butyl‐substituted phthalocyanine in C 60 ‐saturated o ‐xylene under illumination with low‐energy photons. The proposed experimental approach, which focuses on concentrated solutions and is applicable to multicomponent systems, is discussed as a potential tool of materials science.

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