Identifying the Elusive Framework Niobium in NbS‐1 Zeolite by UV Resonance Raman Spectroscopy | Zendy

Chen Yong | Zendy; Wang Xinping | Zendy; Zhang Lejian | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Identifying the Elusive Framework Niobium in NbS‐1 Zeolite by UV Resonance Raman Spectroscopy

Author(s) -

Chen Yong,

Wang Xinping,

Zhang Lejian

Publication year - 2017

Publication title -

chemphyschem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.016

H-Index - 140

eISSN - 1439-7641

pISSN - 1439-4235

DOI - 10.1002/cphc.201700873

Subject(s) - raman spectroscopy , niobium , resonance raman spectroscopy , resonance (particle physics) , zeolite , chemistry , natural bond orbital , spectroscopy , analytical chemistry (journal) , photochemistry , materials science , catalysis , density functional theory , optics , computational chemistry , atomic physics , organic chemistry , physics , quantum mechanics

It was found that bands at 739, 963, and 1107 cm −1 in the resonant Raman spectra are characteristics of framework penta‐coordinated Nb V −OH species, and that a band at 1336 cm −1 in the UV Raman spectrum with excitation line at 320 nm is a sensitive detector for identifying extra‐framework niobium species. The change of framework penta‐coordinated Nb V −OH species into Nb + and NbO − species due to dehydration was definitively confirmed based on UV resonance Raman and UV/Vis results.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research